课题组围绕能源化工领域研究课题，组建了基于扩散排序谱（DOSY NMR）、纯化学位移谱（pure shift）、选择性激发全相关谱（Sel-TOCSY），等高级NMR技术的均相催化表征方法，完成了生物炼制反应中的催化活性位指认、原位反应监控、复杂混合组分定性/定量分析等多项系统性研究工作；通过DOSY技术在低温、无水、无氧的极端条件下捕获了催化剂与糖基底物形成的活性中间体；研究成果从原子层面解答了生物炼制领域普遍关注的催化机理不清晰、产物选择性调控难等关键科学问题；据此提出并确立了NMR for Biorefinery研究方向。以第一或（共同）通讯作者在Applied Catalysis B, Chemical Engineering Journal, Green Chemistry, ACS Sustainable Chemistry & Engineering, Green Energy & Environment等期刊上发表论文60余篇，申请发明专利20项。作为第一指导教师培养硕士研究生18人、博士研究生4人。

1.基金项目

(1) 国家自然科学基金面上项目，No.: 22075308, “NMR研究D-乙酰氨基葡萄糖脱水制含氮呋喃化学品的机理及产物调控”，2021-2024，主持

(2) 国家自然科学基金-山西煤基低碳联合基金培育项目，No.: U1710106, “NMR研究褐煤基吸附剂处理费托合成水的吸附性能及分子间作用机制”, 2018-2020，主持

(3) 山西省重点研发计划(国际合作)，No.: 201703D421041，“含氮生物质制备吡嗪类化合物的研究”，2017-2019，主持

(4) 山西省基础研究计划（青年科技研究基金），No.: 2012021009-2，“氯化锌溶液中甲壳素类生物质降解制备吡嗪类化合物研究”，2012-2014，主持

(5) 中央引导地方科技发展资金项目，No.: 2020ZY0010，“膜分离-离子交换-柱层析耦合分离褐煤解聚产物制高值有机酸”，2020-2022，合作单位项目负责人

(6) 国家重点基础研究发展计划（973计划），No.: 2012CB215305，糖类衍生物催化制含氧燃料的基础研究; 2012-2016，参与

2.代表性论文

(1) Xiaoying Guo, Yan Qiao, Zonglin Yi, Christian Marcus Pedersen, Yingxiong Wang,* Xiaodong Tian,* Peide Han*, Furfural residues derived nitrogen-sulfur co-doped sheet-like carbon: an excellent electrode for dual carbon Lithium-Ion capacitors, Green Energy & Environment, 2024, 9, 1427-1439.

(2) Zhaohui Guo, Christian M. Pedersen, Honghong Chang, Yingxiong Wang,* and Yan Qiao*, Highly efficient production and purification of fructose via glucose isomerization by calcium chloride and triethylamine, Green Chemistry, 2023, 25, 6297-6305.

(3) Qi Zhao, Christian Marcus Pedersen, Jiamin Wang, Rui Liu, Yuanli Zhang, Xiuyin Yan, Zhenzhou Zhang, Xianglin Hou, Yingxiong Wang*, NMR Diffusion Analysis of Catalytic Conversion Mixtures from Lignocellulose Biomass Using PSYCHE-iDOSY, Green Energy & Environment, 2023, 8, 1409-1416.

(4) Mengyu Dou, Tiansheng Deng, Shaojun Qing, Zhefan Wang, Ligong Zhou, Xuekuan Li, Xianglin Hou, Yingxiong Wang*, MingXing Tang*, Insight into the Mechanism of Water-Promoted Hydrogenation of Maleic Acid to Succinic Acid on Pd/C catalyst, ACS Sustainable Chemistry & Engineering, 2022, 10, 1653816547.

(5) Rui Li+, Qixuan Lin+, Junli Ren, Zhaohui Guo, Yingxiong Wang*, Xiaobao Yang*, Xingjie Wang, Insights into the synergistic effect of catalyst acidity and solvent basicity for effective production of pentose from glucose, Chemical Engineering Journal, 2022, 442, 136224.

(6) Hui Ma, Christian M. Pedersen, Qi Zhao, Shiyu Jia, Bin Yuan, Xianglin Hou*, Yingxiong Wang*, Utilizing 3D DOSY NMR in the characterization of organic compounds in coal chemical wastewater", Magnetic Resonance Letters, 2022, 2, 69-79.

(7) Zhaohui Guo, Christian Marcus Pedersen, Pengfei Wang, Minjun Ma, Yingqing Zhao, Yan Qiao*, Yingxiong Wang*, D-Glucose Isomerization with PAMAM Dendrimers as Environmentally Friendly Catalysts, Journal of Agricultural and Food Chemistry, 2021, 69, 5105–5112.

(8) Bihua Chen, Man Wang, Xin Wang, Qi Zhao, Yingxiong Wang*, Guohua Gao*, Poly(ionic liquid)s with superior swelling and enrichment properties in solvents, Polymer Chemistry, 2021, 12, 2731-2742.

(9) Pengfei Liu, Jiaojiao Zhang, Yan Qiao, Xianglin Hou, Yu Liu,* Yingxiong Wang*, Amino Acid Ionic Liquids Catalyzed D-Glucosamine into Pyrazine Derivatives: Insight from NMR spectroscopy, Journal of Agricultural and Food Chemistry, 2021, 69, 24032411.

(10) Qi Zhao, Hui Ma, Christian M. Pedersen, Mengyu Dou, Yan Qiao, Xianglin Hou, Yongqin Qi, Yingxiong Wang*, Pure shift NMR: Application of 1D PSYCHE and 1D TOCSY-PSYCHE Techniques for Directly Analyzing the Mixtures from Biomass-derived Platform Compound Hydrogenation/hydrogenolysis, ACS Sustainable Chemistry & Engineering, 2021, 9, 2456–2464.

(11) Pengfei Liu, Christian Marcus Pedersen, Jiaojiao Zhang, Rui Liu, Zhenzhou Zhang, Xianglin Hou,* Yingxiong Wang*, Ternary deep eutectic solvents catalyzed D-glucosamine self-condensation to deoxyfructosazine: NMR study, Green Energy & Environment, 2021, 6, 261-270.

(12) Qi Zhao, Yu Liu, Hui Ma; Yan Qiao, Jianbin Chao, Xianglin Hou, Yuqi Wang, Yingxiong Wang,* Combination of Pure Shift NMR and Chemical Shift Selective Filters for Analysis of Fischer-Tropsch Waste-water, Analytica Chimica Acta, 2020, 1110, 131-140.

(13) Lingyu Jia, Yan Qiao, Christian Marcus Pedersen, Shiyu Jia, Hui Ma, Zhenzhou Zhang,* Yingxiong Wang,* Xianglin Hou*, Mechanistic Study on the Conversion of D-Fructose into Deoxyfructosazine: Insights from NMR and DFT Study, Chemical Engineering Science, 2020, 214, 115444.

(14) Hui Ma, Yan Qiao, Christian Marcus Pedersen, Pengfei Wang, Mengjie Wu, Pengfei Liu, Xianglin Hou, Tuoping Hu, Yingxiong Wang*, The interaction between Fischer-Tropsch wastewater and humic acid: a NMR study of butanol isomers, Fuel Processing Technology, 2018, 179, 296-301.

(15) Mengjie Wu, Hui Ma, Zhongyi Ma, Yufang Jin, Chunyan Chen, Xiaoya Guo, Yan Qiao, Christian Marcus Pedersen, Xianglin Hou, Yingxiong Wang*, Deep Eutectic Solvents: green solvents and catalysts for the preparation of pyrazine derivatives by self-condensation of D-glucosamine, ACS Sustainable Chemistry & Engineering, 2018, 6, 9434–9441.

(16) Zexiang Lyu, Fen-e Gao, Lizhu Wen, Kemeng Shi, Minjun Ma, Chunju Li, Yingxiong Wang,* Yan Qiao*, DOSY plus selective TOCSY: an efficient NMR combination for analyzing hydrogenation/hydrogenolysis mixtures of biomass-derived platform compounds, Energy & Fuels, 2018, 32 (3), 3551–3558.

(17) Fen Yue, Christian Marcus Pedersen, Xiuyin Yan, Yequn Liu, Danlei Xiang, Caifang Ning, Yingxiong Wang,* Yan Qiao* NMR Studies of Stock Process Water and Reaction Pathways in Hydrothermal Carbonization of Furfural Residue, Green Energy & Environment, 2018, 3, 163-171.

(18) Lingyu Jia, Xingchen Liu, Yan Qiao, Christian Marcus Pedersen, Zhenzhou Zhang, Hui Ge, Zhihong Wei, Yanyan Chen, Xiaodong Wen, Xianglin Hou* and Yingxiong Wang*, Mechanism of the self-condensation of GlcNH2: insights from in Situ NMR spectroscopy and DFT study, Applied Catalysis B: Environmental, 2017, 202, 420429.

(19) Lingyu Jia, Zhenzhou Zhang, Yan Qiao, Christian Marcus Pedersen, Hui Ge, Zhihong Wei, Tiansheng Deng, Jun Ren, Xingchen Liu,* Yingxiong Wang* and Xianglin Hou* “Product distribution control for glucosamine condensation: NMR investigation substantiated by Density-functional calculations”, Industrial & Engineering Chemistry Research, 2017, 56, 29252934.

(20) Yan Qiao, Wenzhi Ge, Lingyu Jia, Xianglin Hou, Yingxiong Wang* and Christian Marcus Pedersen*, “Glycosylation intermediates studied by low temperature 1H- and 19F-DOSY NMR: new insight into the activation of trichloroacetimidates”, Chemical Communications, 2016, 52, 1141811421.

(21) Yan Qiao, Christian Marcus Pedersen, Dongmei Huang, Wenzhi Ge, Mengjie Wu, Chunyan Chen, Shiyu Jia, Yingxiong Wang,* and Xianglin Hou*, “NMR study of the hydrolysis and dehydration of inulin in water: Comparison of the catalytic effect of Lewis acid SnCl4 and Brønsted acid HCl”, ACS Sustainable Chemistry & Engineering, 2016, 4, 3327–3333.

(22) Wenzhi Ge, Jennifer Hongyang Zhang, Christian Marcus Pedersen, Tingting Zhao, Fen Yue, Chunyan Chen, Pengfei Wang, Yingxiong Wang,* Yan Qiao,* “DOSY NMR: A versatile analytical chromatographic tool for lignocellulosic biomass conversion”, ACS Sustainable Chemistry & Engineering, 2016, 4, 11931200.

(23) Lingyu Jia, Christian Marcus Pedersen, Yan Qiao, Tiansheng Deng, Pingping Zuo, Wenzhi Ge, Zhangfeng Qin, Xianglin Hou*, and Yingxiong Wang*, “Glucosamine condensation catalysed by 1-ethyl-3-methylimidazolium acetate: mechanistic insight from NMR spectroscopy”, Physical Chemistry Chemical Physics, 2015, 17, 2317323182.

(24) Yan Qiao, Shuai Chen, Ying Liu, Haizhen Sun, Shiyu Jia, Junyan Shi, Christian Marcus Pedersen, Yingxiong Wang*, Xianglin Hou*, “Pyrolysis of chitin biomass: TG-MS analysis and solid char residue characterization”, Carbohydrate Polymers, 2015, 133, 163170.

(25) Yingxiong Wang, Christian Marcus Pedersen, Yan Qiao, Tiansheng Deng, Jing Shi, Xianglin Hou* “In situ NMR spectroscopy: Inulin biomass conversion in ZnCl2 molten salt hydrate medium - SnCl4 addition controls product distribution”, Carbohydrate Polymers, 2015, 115, 439–443.

3.授权专利

(1) 王英雄、赵建成、侯相林，一种制备3-乙酰氨基-5-乙酰基呋喃的方法，中国，ZL202210142202.4

(2) 王英雄、赵建成、侯相林、张宁，一种以D-乙酰氨基葡萄糖转化制色原体三的方法，中国，ZL202210173017.1

(3) 王英雄、刘鹏飞、侯相林，一种利用离子液体催化制备2,5-脱氧果糖嗪的方法，中国，ZL201910443072.6

(4) 王英雄、贾玲玉、侯相林、乔岩、秦张峰，一种利用甲壳素类生物质制备脱氧果糖嗪的方法，中国，ZL201510849590.X

(5) 王英雄、贾玲玉、侯相林、齐永琴、乔岩，一种利用甲壳素类生物质制备含氮杂环化合物的方法，中国，ZL201410165325.5

(6) 侯相林、王英雄、邓天昇、贾玲玉、乔岩，利用菊粉类生物质生产5-羟甲基糠醛或乙酰丙酸的方法，中国，ZL201410165312.8

(7) 侯相林、王英雄、贾时宇、邓天昇、王玉琪、乔岩，利用甲壳素类生物质生产5-羟甲基糠醛的方法，中国，ZL201310055975.X

4.出版专著

Hui Ma, Yu Liu, Yingxiong WANG*, “Ionic Liquid-Based Adsorbents for the Removal of Toxic Dyes from Wastewater” in “Encyclopedia of Ionic Liquids”, Published by Springer-Nature. 2019,https://doi.org/10.1007/978-981-10-6739-6_101-1

5.学术报告

(1) 报告题目：高级液体核磁共振技术在能源和化学品领域的应用，主办单位：全科盟新能源研究所（大同）； 2019-11

(2) 报告题目：“分析技术大家讲”第十四讲，题目：液体核磁共振技术在能源化学品领域的应用，主办单位：中科院煤化所人事教育处； 2019-11

(3) 报告题目：Nuclear Magnetic Resonance (NMR) for Biorefinery in Green Solvents，由中国化工学会离子液体专业委员会和中国科学院过程工程研究所共同主办的“2020国际绿色技术培训班”； 2020-03

(4) 中国科学院化学研究所 分析测试中心论坛；2021-05

(5) 中国科学院大连化学物理研究所“能源催化材料表征技术研讨会”；2021-07

(6) 2024-01-09 2024年电子顺磁共振（京区）研习班与波谱学前沿讲座；2021-01

6.学术奖励

2017年获中国分析测试协会科学技术奖（CAIA奖）二等奖；排名1/10

2013年获山西省科学技术奖自然科学二等奖，排名5/6